An Ir(IV)-containing polyoxometalate.
نویسندگان
چکیده
[HIr(IV)W6O24](7-), representing the first Ir-containing Anderson-Evans-type polyanion and the first structurally characterized Ir(IV)-based polyoxometalate, has been isolated as its hydrated sodium salt and characterized by single-crystal X-ray diffraction, mass spectrometry, and IR, UV-Vis and EPR spectroscopy. Cyclic voltammetry indicates that the Ir(IV) ions in [HIrW6O24](7-) can undergo reversible one-electron reduction and oxidation, resulting in Ir(III) and Ir(V) derivatives.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 7 شماره
صفحات -
تاریخ انتشار 2015